Analytisch-chemische evaluering van de VG Plasma Quad 2 plus ICP-MS, gemodificeerd met een "high performance" interface
van der Velde-Koerts, T ; de Boer, JLM
Citations
Series / Report no.
Open Access
Type
Language
Date of publication
Year of publication
Research Projects
Organizational Units
Journal Issue
Title
Translated Title
Published in
Abstract
Abstract niet beschikbaar
At the end of 1991 the interface part of the VG Plasma Quad 2 plus ICP-MS was modified. This report describes the performance and the level of molecular interferences of the modified ICP-MS apparatus. The apparatus was optimized for maximal sensitivity, maximal stability and minimal contribution of molucular interferences. Detection limits were four to ten times better than with the standard ICP-MS apparatus and ranged from 6 ng/l for Cd to 1,3 mug/l for B. Using indium as an internal standard, the short term stability was <2% RSD and the long term stability was <4% RSD for elements in the mass range m/z = 51-208. Li, Be, B, Bi and Th had higher RSD values due to unsuitability of the internal standard and to memory effects. The precision ranged from 33% RSD at the detection limit to 0.2-0.7% RSD at 1000x higher concentrations (m/z=51-208). Calibration curves were linear up to at least 200 mug/l. Spectral interferences due to compounds of Na, Cl, S, Ca or Mg prevented the analysis of V, Cr, Ni, Cu, Zn, As and Se at low concentration levels (<20 mug/l.)
