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dc.contributor.authorZhang, Ya-Nan
dc.contributor.authorZhao, Jianchen
dc.contributor.authorZhou, Yangjian
dc.contributor.authorQu, Jiao
dc.contributor.authorChen, Jingwen
dc.contributor.authorLi, Chao
dc.contributor.authorQin, Weichao
dc.contributor.authorZhao, Yahui
dc.contributor.authorPeijnenburg, Willie J G M
dc.date.accessioned2019-02-18T11:46:35Z
dc.date.available2019-02-18T11:46:35Z
dc.date.issued2019-01-23
dc.identifier.issn2050-7895
dc.identifier.pmid30620012
dc.identifier.doi10.1039/c8em00473k
dc.identifier.urihttp://hdl.handle.net/10029/622785
dc.description.abstractEstuarine waters of variable compositions are sinks for many micropollutants. The varying water properties can impact the photodegradation of organic pollutants. In this study, the combined effects of dissolved organic matter (DOM), pH, ionic strength, and halides on the photodegradation of the model organic pollutant oxytetracycline (OTC) were investigated. Suwannee River natural organic matter (SRNOM) was used as a representative DOM. The results showed that the observed photolysis rate constant (kobs) of OTC increased rapidly upon increase of pH. SRNOM induced a 11.0-17.9% decrease of the kobs for OTC. In the presence of SRNOM, the ionic strength and specific halide effects promote OTC photodegradation with a 39.2-84.2% and 7.1-28.8% increase of the kobs, respectively. The effects of SRNOM, ionic strength and halides on OTC photodegradation are pH-dependent. Direct photolysis half-lives (t1/2) of OTC were estimated in view of the more important role of direct photolysis compared to indirect photolysis. The estimated t1/2 values decreased from 187.4-206.6 d to 34.4-36.6 d as the pH increases in the Yellow River estuarine region. The results of this research demonstrate that the photodegradation rate of OTC increases rapidly in the gradient from river water to marine water in estuarine regions.en_US
dc.language.isoenen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen
dc.titleCombined effects of dissolved organic matter, pH, ionic strength and halides on photodegradation of oxytetracycline in simulated estuarine waters.en_US
dc.typeArticleen_US
dc.identifier.journalEnviron Sci Pricess Impacts 2019; 21(1):155-62en_US
dc.source.journaltitleEnvironmental science. Processes & impacts


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